P. Bukovec, J. Šiftar
Nov 1, 1975
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0
Influential Citations
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Journal
Monatshefte für Chemie / Chemical Monthly
Abstract
Sodium hexafluoromanganate(III) has been synthesized by heating equimolecular quantities of Na2MnF5 and NaF in argon atmosphere. The compound is monoclinic witha=5.56 (1) Å,b=5.84 (1) Å,c=8.10 (2) Å, β=90.7 (2)δ andZ=2. It is a high spin complex withμeff and the deformation of the octahedra is evident from its IR-spectra. Two enantiotropic transitions (at 562 and 653°C) and the melting point at 800°C have been observed.