S. Aiken, C. Gabbutt, B. Heron
Nov 1, 2021
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Journal
Dyes and Pigments
Abstract
Abstract A series of ketohydrazone dyes has been synthesised from 4-morpholino-2-naphthol and ortho-substituted anilines by conventional diazotisation coupling chemistry. Whilst the new, dull orange-red, dyes exhibit only a minor variation of absorption maxima across the range of substituents, they are hyperchromic relative to Sudan 1 and their none ortho-substituted analogue. Protonation of selected dye examples results in a bathochromic and hyperchromic shift in absorption maxima to afford vibrant purple-coloured protonated species.