J. Arpalahti
Nov 1, 1990
Citations
0
Influential Citations
13
Citations
Journal
Inorganic Chemistry
Abstract
Kinetics of the complex formation between aquated cis-Pt II (NH 3 ) 2 and inosine or 1-methylinosine has been studied by HPLC in aqueous solution over a pH range of 4.1-8.6 at 298.2 K. The complexation of aquated cis-Pt II (NH 3 ) 2 can be completely explained by substitution of the aqua ligand(s) with incoming nucleosides. Deprotonation of one of the aqua ligands results in a 10-fold decrease in the displacement rate of the remaining one