G. M. Nazin, G. Manelis, F. I. Dubovitskii
Jun 1, 1971
Citations
0
Influential Citations
1
Citations
Journal
Russian Chemical Bulletin
Abstract
1. The kinetic parameters and composition of the decomposition products of 1-chloro-1, 1-dinitro-, 1-bromo-1, 1-dinitro-, 1, 1-dichloro-1-nitroethane, and 1, 1-dichloro-1-nitropropane are evidence of a radical mechanism of the decomposition of these compounds with primary cleavage of the C-N bond. 2. When an NO2 group in the compound RC(NO2)3 is replaced by Cl or Br atoms, the activation energy is practically unchanged, but the preexponential factor is significantly reduced.