J. F. Read, S. Bewick
2005
Citations
0
Influential Citations
5
Citations
Journal
BioInorganic Reaction Mechanisms
Abstract
The kinetics and mechanism of the reaction between a series of inorganic oxysulfur compounds and potassium ferrate have been studied. Although a clear pattern has been developed, there are certain anomalous results, often pH dependent, which could be occurring because of hydrolysis or impurities. This paper addresses this problem by examining four theoretical models applied to some of the kinetic results obtained for trithionate, tetrathionate and pentathionate ions. The models examined are: