V. Y. Korobkov, E. N. Grigorieva, V. I. Bykov
Aug 1, 1995
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Journal
Fuel Processing Technology
Abstract
Kinetics and mechanism of thermolysis of 1-phenyl-2-(4-pyridyl)ethane have been studied and the thermolysis rate constants of its two isomers have been calculated. The calculated and experimentally determined thermolysis rate constants of 1-phenyl-2-(3-pyridyl)ethane agree well. Compared with 1,2-diphenylethane, the introduction of heteroatom, nitrogen into meta position accelerated the thermolysis slightly, but retarded it into para- and ortho-position.