K. Jackson, J. Ridd, M. Tobe
Aug 14, 1979
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0
Influential Citations
1
Citations
Journal
Journal of The Chemical Society-perkin Transactions 1
Abstract
The methoxydechlorination of 5-chloro-1,10-phenanthroline occurs readily in DMSO–MeOH (89.9–10.1 w/w) at ca. 60 °C and is without significant side reactions. The dependence of the reaction rate on the concentration of methoxide ions has been determined at several temperatures and the rate has been shown to accord with that expected on the addition–elimination mechanism. Under similar conditions, mono and di-alkylated derivatives are deactivated by addition of methoxide ion to the 2-position, and undergo no methoxydechlorination.