F. P. Sidel'kovskaya, A. Avetisyan, M. F. Shostakovskii
Apr 1, 1965
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Journal
Russian Chemical Bulletin
Abstract
1. A method was developed for the synthesis of N-allyl thio lactams by the reaction of N-allyl lactams with phosphorus pentasulfide. 1-Allyl-2-pyrrolidinethione, 1-allyl-2-piperidinethione, and N-allylthiocaprolactam were prepared. 2. By the action of allyl bromide on the sodium salts of 2-pyrrolidinethione and thiocaprolactam, the corresponding S-allyl thio lactams were synthesized. 3. The infrared and ultraviolet spectra of the S- and N-allyl thio lactams were studied. 4. Preliminary experiments were carried out on the polymerization and copolymerization of the above unsaturated compounds.