W. Herrmann, R. Anwander, M. Kleine
Nov 1, 1992
Citations
0
Influential Citations
26
Citations
Journal
Chemische Berichte
Abstract
Complexes of the Lanthanides, II[1]. – Tris(tert-butylcyclopentadienyl)neodymium, -dysprosium, and -thulium. Crystal and Molecular Structure of Bis(tert-butylcyclopentadienyl)hydroxidoneodymium and -dysprosium NdCl3, DyCl3, and TmI3 (1a–c) react with the potassium salt K(tBuCp) (2) of tert-butylcyclopentadiene in THF to yield the sublimable homoleptic tris(tert-butylcyclopentadienyl) complexes of formula Ln(tBuCp)3 (3a–c). The thermal behavior makes these compounds potential precursors for chemical vapour deposition techniques (MOCVD).