J. Lam, Yuping Dong, K. Cheuk
Jan 15, 2002
Citations
0
Influential Citations
56
Citations
Journal
Macromolecules
Abstract
Biphenyl- (Biph-) containing 1-alkynes (3 and 4) and their polymers (1 and 2) with varying bridge groups and spacer lengths were synthesized and the effects of the structural variation on their properties, especially their mesomorphism and photoluminescence behaviors, were studied. The acetylene monomers 3(3) [HC⋮C(CH2)3O−Biph−OCO(CH2)10CH3] and 4(m) [HC⋮C(CH2)mOCO−Biph−OCO(CH2)10CH3, m = 3, 4] were prepared by sequential etherization and esterification reactions of 1-alkynes. While 3(3) exhibits enantiotropic crystal E and SmB mesophases, its structural cousin 4(3) displays only a monotropic SmB phase. Enantiotropic SmA and SmB mesophases are, however, developed when the spacer length is increased to 4. Polymerizations of the monomers are effected by Mo-, W-, Rh-, and Fe-based catalysts, with the WCl6−Ph4Sn catalyst giving the best results (isolation yield up to 85% and Mw up to 59000). The polymers were characterized by IR, UV, NMR, TGA, DSC, POM, XRD, and PL analyses. Compared to 1(3), 2(3) shows a red...