E. Pastushenko, D. Kurbanov, S. S. Zlotskii
Dec 1, 1983
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Journal
Chemistry of Heterocyclic Compounds
Abstract
In the presence of tert-butyl peroxide, 2-dimethylamino-1,3-dioxacyclanes are converted to esters of dimethylcarbamic acid. The reaction is described by a kinetic equation for an unbranched chain reaction with quadratic chain termination. The five-membered heterocycle is more reactive than the six-membered heterocycle. The predominant site for free radical attack is the methine group adjacent to the three heteroatoms.