Hua Wang, Zhongmin Liu, Chenglin Sun
Sep 1, 2004
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0
Influential Citations
6
Citations
Journal
Catalysis Today
Abstract
Abstract Several solid acidic catalysts have been investigated for the Prins condensation of iso-butyl aldehyde with tert-butyl alcohol in a liquid-phase reaction. The results demonstrate that acidic molecular sieves are effective catalysts for the condensation reaction, and HZSM-5 molecular sieves possessed strong enough acidity and proper channel systems exhibit high catalytic performance. Solvent polarity and solvent–active site interaction would significantly affect the aldehyde conversion and the 2,5-dimethyl-2,4-hexadiene selectivity. The iso-butyl aldehyde to tert-BuOH ratio, catalyst amount, solvent amount, reaction temperature, reaction time, Si/Al ratio of HZSM-5 molecular sieves, catalytic performance of different solid acids, and side-reactions in the system are studied. Up to 78.6% iso-butyl aldehyde conversion is obtained with a 57.8% 2,5-dimethyl-2,4-hexadiene yield over HZSM-5 with Si/Al of 39 after 8 h at 160 °C, which provides a useful and economical potential industrial application way on a large scale to manufacture 2,5-dimethyl-2,4-hexadiene.