H. Kricheldorf, S. Böhme, Gert Schwarz
Nov 16, 2001
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0
Influential Citations
52
Citations
Journal
Macromolecules
Abstract
Two series of kinetically controlled polycondensations were conducted yielding polyamides of aliphatic dicarboxylic acids. First, the bis(trimethylsilyl) derivatives of 1,3-diaminobenzene, 4,4‘-diaminodiphenylmethane, 1,12-diamino-4,9-dioxadodecane, and 1,12-diaminododecane were polycondensed with dicarboxylic acid dichlorides in N-methylpyrrodidone below 0 °C. After optimization of the reaction conditions mainly cyclic polyamides were detectable in the MALDI−TOF mass spectra (up to 13 000 Da) of the semiaromatic polyamides in contrast to the Carothers−Flory theory. In the case of silylated aliphatic diamines, side reactions of the acid chlorides prevented a complete conversion of the amino groups, so that the reaction products mainly consisted of cycles and linear chains having two amino end groups. Second, normal interfacial polycondensations were performed either with 1,6-diaminohexane and adipoyl chloride or with 1,12-diaminododecane and decane-1,10-dicarbonyl chloride. When the loss of acid chloride ...