Jian Cao, Maozhong Miao, Wan-li Chen
Oct 19, 2011
Citations
0
Influential Citations
16
Citations
Journal
The Journal of organic chemistry
Abstract
The manganese(III) acetate-mediated free radical cyclization of diarylmethylenecyclopropa[b]naphthalenes with nucleophiles such as carboxylic acid and sulfonic acid provides an efficient method for the synthesis of 1,2-benzanthracenes in moderate to good yields under mild conditions. In addition, after several steps of simple and routine operations, the obtained 1,2-benzanthracenes bearing an acetoxy group could be easily converted to structurally more sophisticated 1,2-benzanthracene derivatives, which are not easily accessible yet potentially useful candidates for materials science.