Takeshi Sakaizumi, Hideki Tanaka, N. Kuze
Jul 1, 1997
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Journal
Journal of Analytical and Applied Pyrolysis
Abstract
Abstract The pyrolysates of bicyclo[2.2.1.]hept-2-ene and its derivatives have been investigated by pyrolysis-mass spectrometry and microwave spectroscopy (Py-MS/MW). The pyrolysates of ethene, s - trans -acrolein, methyl vinyl ketone, methylallene, and isocyanic acid were generated by elimination of cyclopentadiene(Cp) from bicyclo[2.2.1.]hept-2-ene, 2-carboxaldehydebicyclo [2.2.1.]hept-5-ene, 2-acetyl-bicyclo[2.2.1.]hept-5-ene, 2-ethylidene-bicyclo[2.2.1.]-hept-5-ene, and 2-azabicyclo[2.2.1.]hept-5-ene-3-one, respectively.