P. Barili, G. Berti, D. Bertozzi
1990
Citations
0
Influential Citations
15
Citations
Journal
Tetrahedron
Abstract
Abstract Meta-chloroperbenzoic acid can be used as a mild and selective reagent for the removal of the O-propenyl group in the deprotection sequence of allyl protected hydroxyl functions. Its use is illustrated in four synthetic pathways, leading, respectively, to methyl 3-0-acetyl-4- deoxy-6-0-( 1-methoxy-1-methylethyl)-α-L-threo-4-hexenopyranoside, to methyl 2-O-acetyl-3,4,6-tri-O-methyl-α- and β-D-galactopyranoside and to benzyl 6-O-allyl-3,4-0-isopropylidene-β-D-galactopyranoside.