J. C. Trebellas, J. R. Olechowski, H. B. Jonassen
Oct 1, 1966
Citations
0
Influential Citations
34
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The cis-1,2-divinylcyclohexane complexes of palladium(II) and platinum(II) were prepared at ambient temperature from bisbenzonitrilepalladium(II) dichloride and sodium chloroplanitinate by the metal-catalyzed rearrangement of cis, trans-1,5-cyclodecadiene. The mechanism by which the rearrangement could have occured is discussed and a closed ring π-allylic intermediate proposed.