D. Clarke, R. Kemmitt, D. Russell
Jul 15, 1975
Citations
0
Influential Citations
3
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Hexafluorobut-2-yne reacts with chloro(cycloocta-1,5-diene)iridium(I) dimer at 20 °C to give a complex [IrCl(cod)(C4F6)]2 in which both the diene and the acetylene are π-coordinated to the same iridium atom; an isomeric product, [IrCl(CCF3CHCF3)(C8H11)]2, is isolated from the same reactants at 90 °C.