B. Alcaide, P. Almendros, Carlos Lázaro‐Milla
Apr 7, 2015
Citations
0
Influential Citations
18
Citations
Journal
Chemical communications
Abstract
1,2-Dipole Tf2C=CH2 is generated in situ and immediately reacts at room temperature with an azide to afford previously unknown 4-trifluoromethanesulfonyl 1,2,3-triazoles through a stepwise [3+2] cycloaddition reaction. Noteworthily, this mild and powerful uncatalyzed protocol is highly regio- and chemoselective.