T. Agapie, P. Diaconescu, C. Cummins
Mar 20, 2002
Citations
0
Influential Citations
56
Citations
Journal
Journal of the American Chemical Society
Abstract
Methine (CH) transfer to an open coordination site was achieved in one pot by titanium(III) abstraction of Cl from 7-chloronorbornadiene, radical capture by Mo, and benzene extrusion. This efficient Mo methylidyne synthesis permitted elaboration to an anionic phosphaisocyanide derivative upon deprotonation, functionalization with dichlorophenylphosphine, and ultimate reduction.