S. Mori, T. Aoyama, T. Shioiri*
1986
Citations
0
Influential Citations
16
Citations
Journal
Tetrahedron Letters
Abstract
Tilivalline (1), a metabolite from Klebsiella, has been efficiently and stereoselectively synthesized from diphenyl phosphorazidate (DPPA), the 2-oxazoline 2, the L-proline derivative 5, and indole: the key step is a Mannich type intramolecular cyclization accompanied with simultaneous and completely stereoselective introduction of indole.