H. Rao, S. Rajamathe, S. Raj
Sep 15, 1999
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Journal
Acta Crystallographica Section C-crystal Structure Communications
Abstract
In the title compounds, methyl 1-(4-chlorobenzyl)-2-oxocyclohexane-1-carboxylate, C 15 H 17 ClO 3 , (I), and methyl (2RS ,4aRS ,8aRS)-2-(4-chlorobenzyl)-3-oxoperhydronaphthalene-2-carboxylate, C 19 H 23 ClO 3 , (II), the cyclohexane rings adopt chair conformations. In (I), the carboxylate group is attached in an axial position and in (II), it is in a biaxial position. The dihedral angles between the mean planes through the cyclohexane ring and the phenyl substituent are 48.89 (9) and 24.61 (10)° in (I) and (II), respectively.