J.R.C. Light, H. Zeiss
Feb 1, 1970
Citations
0
Influential Citations
33
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Methylmagnesium chloride reacts with the chlorides of Ti III , Ti IV , Zr IV , V III , Nb V , Cr III , Cr III , Mn II , Fe III , Ru III , Co II , Rh III , Ni II , Pd II , Pt II , Cu I , Cu II , Au III and Zn II at -70° in tetrahydrofuran to give methyl-transition metal reagents. These reagents react with diphenylacetylene giving methylation and hydrogenation products, as well as oligomerization.