Q. Huang, Gui Li, Haiyang Zhang
Jun 1, 2014
Citations
0
Influential Citations
15
Citations
Journal
Zeitschrift für anorganische und allgemeine Chemie
Abstract
The heptanuclear cobalt cluster [Co7(emmp)6(CH3O)6]·(ClO4)2 (1) (Hemmp = 2-ethyliminomethyl-6-methoxy-phenol) was synthesized by the microwave-assisted reaction of Co(ClO4)2·6H2O with 3-ethoxy-2-hydroxy-benzaldehyde (Hehb) and ethylamine in mixed solvent (acetonitrile:methanol = 1:1). Complex 1 was characterized by IR spectroscopy, elemental analysis, and X-ray single-crystal diffraction. The magnetic properties of 1 are discussed. Complex 1 displays dominant ferromagnetic interactions from the nature of the binding modes through μ3-OCH3 and μ2-phenoxo.