T. George, J. Debord, K. Heier
Sep 15, 1997
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Journal
Acta Crystallographica Section C-crystal Structure Communications
Abstract
The crystal structure of [bis(2-diphenylphosphinoethyl)phenylphosphine-P,P',P][bis(diphenylphosphino)-methane-P,P'] carbonylmolybdenum(0), [Mo(dpepp)-(dppm)(CO)] [where dppm = Ph 2 PCH 2 PPh 2 and dpepp = Ph 2 PCH 2 CH 2 P(Ph)CH 2 CH 2 PPh 2 ], is reported. In the distorted octahedral complex, the tridentate ligand adopts a facial arrangement with the monodentate ligand trans to the central P atom. All Mo-P distances are statistically dissimilar.