Martin Brenda, A. Greiner, W. Heitz
May 1, 1990
Citations
0
Influential Citations
28
Citations
Journal
Macromolecular Chemistry and Physics
Abstract
Poly(1,4-phenylenevinylene) was obtained by reacting dibromoarenes with ethylene in a palladium-catalyzed reaction. Defects of the polymer structure were elucidated by model reactions. Side reactions in the reaction of halogenated arenes and ethylene or styrene, catalyzed by Pd, could be minimized by low catalyst concentrations and low reaction temperatures. The Pd-catalyzed reaction of aroyl chlorides with ethylene or styrene was probed by model reactions