B. Marciniec, H. Maciejewski, K. Szubert
Apr 20, 2006
Citations
0
Influential Citations
24
Citations
Journal
Monatshefte für Chemie / Chemical Monthly
Abstract
Summary.The hydrosilylation of 1-heptene, allyl glycidyl ether and, allyl polyether by heptamethylhydrotrisiloxane and poly(hydro, methyl)(dimethyl)siloxane catalyzed by rhodium(I) complexes (particularly [{Rh(μ–OSiMe3)(cod)}2]) in imidazolium ionic liquids (especially [TriMIM]MeSO4) gives heptyl and glycidyloxy functional (poly)siloxanes and silicone polyethers with high yield and selectivity. The catalytic system based on rhodium siloxide can be easily separated from the product and successfully reused up to five times.