John. A. Soderqulst, S.-J. Hwang-Lee, C. Barnes
1988
Citations
0
Influential Citations
9
Citations
Journal
Tetrahedron Letters
Abstract
Abstract The single crystal X-ray structure of monoisopinocampheylborane-N,N,N',N'-tetramethylethylenediamine (TMEDA) complex (2:1) was determined. From the conformational features of this complex, a model for the origin of the asymmetric induction with IPCBH, is proposed which explains the observed selectivity of the reagent in the hydroboration of differing alkene types.