Siti Sarah Abdul Rahman, D. Kawaguchi, Y. Matsushita
Jan 7, 2011
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Influential Citations
12
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Journal
Polymer
Abstract
Abstract The molecular characteristics of poly(4- tert -butoxystyrene) (O) upon hydrolysis reaction were investigated. It is known that O can be converted into poly(4-hydroxystyrene) (H) through hydrolysis reaction using strong acid. In this study, a set of poly(4- tert -butoxystyrene- co -4-hydroxystyrene)s (O/H copolymers) having various conversion rates, f H s, were prepared. Hydrolysis reaction is found to occur uniformly by matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF MS) where the average f H obtained was consistent with that from 1 H NMR though a certain distribution in the number of hydrolyzed units was conceived. Monomer sequence of O/H copolymers was determined by 13 C NMR and the changes in triad concentration were obtained by spectra subtraction method. As a result, 13 C NMR reveals that O and H are statistically distributed. To evaluate the effect of hydrolysis on microphase-separated structure, we observed the morphology of partially hydrolyzed poly(4- tert -butylstyrene- block -4- tert -butoxystyrene) (BO) by transmission electron microscopy (TEM) and small-angle X-ray scattering (SAXS). Samples with f H from 0.21 to 0.67 form both lamellar (major component) and cylindrical (minor component) structures reflecting both the statistical manner of hydrolysis reaction and the possible localized distribution of H sequence.