Ansoo Lee, S. So, A. Lough
Oct 1, 2014
Citations
0
Influential Citations
2
Citations
Journal
Asian Journal of Organic Chemistry
Abstract
“Mother diamine” (MD) or 1,2-bis(2-hydroxy-phenyl)ethylenediamine can be rapidly transformed to a wide variety of chiral ligands including vicinal diamines and analogs of binol (MDdiol), binap (MDdiphos), and monophos (MDphos). The reactivity and stereoselectivity of the MDphos ligands in Rh-catalyzed hydrogenation are highly sensitive to the N,N′-dialkyl substituents.