D. Scholz
Feb 13, 1984
Citations
0
Influential Citations
17
Citations
Journal
European Journal of Organic Chemistry
Abstract
4-Methylbenzolthiosulfonsaure-S-alkylester, darstellbar aus dem kauflichen Kaliumsalz der 4-Methylbenzolthiosulfonsaure durch Umsetzen mit Alkylbromiden oder -iodiden in wasserfreiem Dimethylformamid, thiolieren die Enolate cyclischer Ketone in α-Position in hohen Ausbeuten. New Synthetic Methods, 9. — S-Alkyl 4-Methylbenzenethiosulfonates, Excellent Reagents for α-Thiolation of Cyclic Ketones S-Alkyl 4-methylbenzenethiosulfonates, easily prepared by alkylation of commercially available potassium 4-methylbenzenethiosulfonate in dry dimethylformamide, thiolate enolates of cyclic ketones in α position in high yield.