K. Ogawa, S. Rasmussen
Feb 3, 2006
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Quality indicators
Journal
Macromolecules
Abstract
Oxidative polymerization studies of N-functionalized dithieno[3,2-b:2‘,3‘-d]pyrroles (where substituent = hexyl, octyl, decyl, octadecyl, tert-butyl, 2-ethylhexyl, or p-hexylphenyl) via both chemical oxidation and electropolymerization are presented. While electropolymerized samples are insoluble, it is possible to isolate soluble materials via chemical oxidation methods. Solution and solid-state characterization of the resulting polymeric materials is described, including photophysical and electrochemical studies, and these properties are compared to related polythiophene materials. In addition to reduced band gaps (∼1.7 eV), these materials exhibit good red emission with solution quantum efficiencies up to 34%.