V. P. Sheverdov, O. V. Ershov, O. Nasakin
Sep 1, 2001
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Journal
Russian Journal of General Chemistry
Abstract
Probably, at the nitration of cyclohexanones Ia3Ic in the first step occurs nitration of benzene ring in the ortho position to the first mode orienting substituent, the methoxy group. In the second step, at the isolation of compounds IIa3IIc by adding water to the reaction mixture, one cyano group is hydrolyzed. Note that compounds IIIa3IIIc are stable in respect of strong acids (sulfuric and nitric) and ever at elevated temperature no one of the three remaining cyano group was hydrolyzed.