M. Herberhold, H. Kratzer
Nov 1, 1977
Citations
0
Influential Citations
4
Citations
Journal
Zeitschrift für Naturforschung B
Abstract
In contrast to tetranuclear bis(pentane-2,4-dionato)-cobalt(II), Co4(acac)8, which is cleaved by nitric oxide to give the adduct Co(acac)2(NO), the mononuclear tris(pentane-2,4-dionato)cobalt(III), Co(acac)3, is attacked by NO at the chelate ligands. The photonitrosylation of Co(acac)8 in benzene or toluene solution leads to the oximato complex tris(3-hydroxyimino-pentane-2,4-dionato)cobalt.