J. Atwood, S. M. Lawrence, C. Raston
1994
Citations
0
Influential Citations
17
Citations
Journal
Journal of The Chemical Society, Chemical Communications
Abstract
Treatment of N,N′-di-tert-butylethylenediamine with two equivalents of H3AlNMe3 in diethyl ether affords a novel alane-rich amido species [(H2Al)2{µ-N(But)CH2}2]1, whereas with one equivalent a stable, intramolecularly coordinated secondary amine adduct of aluminium dihydride results, [H2[graphic omitted]But]2; the monochloro analogue [Cl(H)[graphic omitted]But]3 is accessible using ClH2AlNMe3, as a mixture of diastereoisomers in solution.