T. Kishimoto, F. Nakatsubo, K. Murakami
Nov 1, 1995
Citations
0
Influential Citations
10
Citations
Journal
Journal of Wood Chemistry and Technology
Abstract
Abstract Methyl 4-O-ethyl-β-D-glucopyranoside (1) was prepared as a model compound for cellulose to investigate the reactions of ozone with polysaccharides during ozone bleaching of kraft pulp. The model compound was converted into authentic carbonyl sugars, methyl 3,6-di-O-acetyl-4-O-ethyl-β-D-arabino-hexopyranosidulose (2), methyl 2,6-di-O-acetyl-4-O-ethyl-β-D-ribo-hexopyranoside-3-ulose (3), methyl 2,3-di-O-acetyl-4-O-ethyl-β-D-gluco-hexodialdo-1,5-pyranoside (4). These carbonyl sugars were converted into O-methyloximes and analyzed by gas chromatography and mass spectrometry.