E. V. Dehmlow, R. Neuhaus
1987
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Journal
Zeitschrift für Naturforschung B
Abstract
Abstract 1.2-Dialkoxytetrachlorocyclopropanes, ortho Esters Primary aliphatic alcohols and HCCl 3 /NaOH/ catalyst yield stereoisomeric 1,2-dialkoxytetra-chlorocyclopropanes 4 and 5, benzyl and phenethyl alcohol give orthoformates (1). Compounds 4 suffer rearrangement/hydrolysis at 120 °C yielding 3-alkoxv-2,3-dichloroacrylates (6).