M. Shimizu, T. Hata, T. Hiyama
Jul 1, 2000
Citations
0
Influential Citations
12
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Fluorotris(trimethylsilyl)methane reacted with 2 mol of aromatic aldehydes in the presence of KF/18-crown-6 to give 1,3-disubstituted 2-fluoro-2-propen-1-ols in one pot. On the other hand, treatment of fluoro(tributylstannyl)bis(trimethylsilyl)methane with BuLi, followed by addition of an aldehyde, produced (1-fluoroalkenyl)trimethylsilanes in moderate to good yields.