M. Shi, Jian Jiang, Gui‐Ling Zhao
Dec 1, 2002
Citations
0
Influential Citations
9
Citations
Journal
European Journal of Inorganic Chemistry
Abstract
A novel chiral silver(I) complex was successfully synthesized from the reaction of chiral (S)-4-isopropylthiazolidine-2-thione ligand (1) with AgOAc in dichloromethane in the presence of Et3N and DMAP at room temperature. Its unique crystal structure was unambiguously disclosed by X-ray analysis. The six silver atoms and six (S)-4-isopropylthiazolidine-2-thione ligands present in the complex are connected through the S and N atoms to form a cluster containing a silver octahedron with six faces of the octahedron capped by ligands. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)