V. Ramkumar, P. Kannan
Aug 1, 2015
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0
Influential Citations
25
Citations
Journal
Optical Materials
Abstract
Abstract Two different novel heterocyclic compounds namely 2,5-bis(1,3-diphenyl-4,5-dihydro-1H-pyrazol-5-yl)thiophene (Material I) and 2,5-bis(3-(naphthalen-1-yl)-1-phenyl-4,5-dihydro-1H-pyrazol-5-yl)thiophene (Material II) were designed, synthesized and characterized by spectral methods. The synthesized materials were confirmed by standard techniques such as FT-IR, 1H NMR and elemental analysis. Physical properties include thermal, surface morphology of the materials were explained from TGA, DSC and SEM analysis. Optical properties such as absorption, emission, solvent effect have been investigated by UV–Visible and fluorescence spectrophotometers. The blue and green emission of the materials was confirmed by using UV light as well as fluorescence spectrophotometers. Bandgap energies of these materials were obtained by both experimental and theoretical calculation from of cyclic voltammetry, UV–Visible spectrophotometer and DFT calculation. I–V characteristic analysis used to determine the threshold voltage (Von) of the two materials. The obtained results of the materials have promising to be applicable for opto-electronic applications.