D. Griffith, Aisleen Haughey, S. Chahal
Jun 20, 2010
Citations
0
Influential Citations
18
Citations
Journal
Inorganica Chimica Acta
Abstract
Reaction of benzisothiazolinone (Bit), a well-known biocide, with the Pd(II) and Pt(II) am(m)ine precursors cis -[Pd(en)(H 2 O) 2 ](NO 3 ) 2 and cis -[Pt(NH 3 ) 2 (H 2 O) 2 ](NO 3 ) 2 yielded cis -Pd(en)(Bit −1H ) 2 and cis -Pt(NH 3 ) 2 (Bit −1H ) 2 , respectively. Bit is bound to the metal centres in both cases through the deprotonated isothiazolinone N . The crystal structures of a Bit/BitO co-crystal and cis -Pd(en)(Bit −1H ) 2 ·H 2 O are also described.