Kuniaki Tatsuta, Satoru Miyashita, Kohji Akimoto
1982
Citations
0
Influential Citations
12
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Methyl 2-amino-2N,3O-(o-benzenedisulfonyl)-2-deoxy-α-D-glucopyranoside, which was prepared from methyl 2-amino-2-deoxy-α-D-glucopyranoside and o-benzenedisulfonyl dichloride, was treated with sodium methoxide to afford exclusively a branched-chain amino sugar, methyl 2,3-dideoxy-3-C-formyl-2-(o-sulfobenzenesulfonyl)amino-α-D-xylofuranoside-3′R,5-hemiacetal sodium salt (6). Some derivatives were synthesized from 6.