Sami Tlais, R. Danheiser
Oct 22, 2014
Citations
0
Influential Citations
38
Citations
Journal
Journal of the American Chemical Society
Abstract
The first synthesis of a strained six-membered cyclic ynamide is described. N-Tosyl-3-azacyclohexyne is generated via fluoride-promoted 1,2 elimination under conditions that allow trapping of the strained heterocyclic alkyne in a variety of addition, insertion, and [2 + 2], [3 + 2], and [4 + 2] cycloaddition reactions.