D. E. Arrington
1975
Citations
0
Influential Citations
4
Citations
Journal
Journal of The Chemical Society-dalton Transactions
Abstract
The preparation of N-(triphenylphosphoranylidene)sulphamoyl azide. Ph3P:N·SO2N3, by reduction of the hydrazide with nitrous acid or by reaction of sodium azide with the chloride in methyl ethyl ketone, is described. The azide reacts with phosphites and thiophosphites to produce compounds of the type Ph3P:N·SO2·N:P(OR)3(R = Me, Et, Prn, Bun, or Ph), and Ph3P:N·SO2·N:P(SR)3(R = Et or Prn), respectively.