M. Sharif, S. Reimann, A. Villinger
Apr 1, 2010
Citations
0
Influential Citations
3
Citations
Journal
Synlett
Abstract
The Suzuki-Miyaura reaction of 1,2-dibromo-3,5-difluorobenzene with two equivalents of arylboronic acids gave difluorinated ortho-terphenyls. The reaction with one equivalent of arylboronic acid resulted in site-selective formation of 2-bromo-3,5-difluoro-biphenyls. The one-pot reaction of 1,2-dibromo-3,5-difluorobenzene with two different arylboronic acids afforded difluorinated ortho-terphenyls containing two different terminal aryl groups.