Martyna Malinowska, Szymon Jarzyński, A. Pieczonka
Aug 17, 2020
Citations
0
Influential Citations
5
Citations
Journal
The Journal of Organic Chemistry
Abstract
Enantiopure aziridin-2-yl methanols 3–7 are used as highly effective sensors for enantiodiscrimination of α-racemic carboxylic acids containing tertiary or quaternary stereogenic centers. A linear correlation between theoretical and observed % ee values for CSA-3 and enantiomerically enriched samples of mandelic acid has been observed, indicating the possible application of these compounds in the ee determination. The free NH and OH groups in 3–7 ensure good recognition.