W. Massa, G. Baum, B.-S Seo
Sep 13, 1988
Citations
0
Influential Citations
9
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Trimethylplatium bromide crystallizes from toluene as [(Me3PtBr)4] · 0.5toluene the structure of which has been determined by X-ray diffraction and shown to be of the cubane type observed in the (Me3PtX)n family. Crystal data: space group C2/m, Z = 4, a 2473.6(3), b 1151.9(1), c 1017.1(1) pm, β 109.42(1)°; mean interatomic distances: PtBr 267.7 pm, PtPt 393.0 pm, BrBr 363.2 pm; mean bond angles: BrPtBr 85.4°, (PtBrPt) 94.3°.