G. Deacon, J. Parrott
Apr 1, 1970
Citations
0
Influential Citations
25
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Bromobis(pentafluorophenyl)thallium(IlI) reacts with many main group elements on heating in the absence of a solvent to give pentafluorophenyl derivatsves of these elements. The compounds C 6 F 5 M (M = Cl, Br, or I), (C 6 F 5 ) 2 M (M = Zn, Cd, Hg, S, Se or Te), (C 6 F 5 ) 3 M (M = In, P, As, or Sb), and (C 6 F 5 )M (M = Ge or Sn) have been prepared by this method. Substantial decomposition of (C 6 F 5 ) 2 TlBr occurs on reaction with aluminium, gallium, lead and bismuth, but pcntafluorophenyl derivatives of thesee´lements are not obtained.