Li Yong, Xiaochun Tao, Fang Qian
Jun 17, 2002
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Influential Citations
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Journal
Journal of Molecular Catalysis A-chemical
Abstract
Abstract Using the catalyst system consisting of an alkenyl-substituted Cp 2 ′TiCl 2 and i -C 3 H 7 MgCl, isoprene can be dimerized to linear dimers 2,6-dimethyl-1- trans -3,6-octatriene and 3,6-dimethyl-1,3,6-octatriene under mild reaction condition. The substituent effects of alkenyl-substituted titanocene catalysts on both the yield and the selectivity were studied.