M. Ochiai, Daisuke Kajishima, T. Sueda
Jul 23, 1999
Citations
0
Influential Citations
28
Citations
Journal
Tetrahedron Letters
Abstract
Abstract tert-Butylperoxyiodane undergoes oxidation of the methylene groups α to the nitrogen atom of amides (or carbamates) yielding imides or tert-butylperoxyamide acetals, depending on the reaction conditions. A proposed mechanism involves generation of carbon-centered radicals α to the nitrogen atom.